A-Level Revise Aid: This resource is designed to support your revision and may contain errors. If you find a discrepancy with your class teaching, your teacher is correct -- please let us know at
alevelrevise@scott.scottrix.co.uk .
Home βΊ
Physics βΊ
Thermal Physics
Exam Board: AQA Pearson Edexcel OCR WJEC / Eduqas CCEA
π Key Points
Key Fact: Internal energy U = Ξ£(KE + PE) of molecules; Temperature β mean KE per molecule
Key Fact: Q = mcDeltaΞΈ (no phase change); Q = mL (phase change); L_fusion, L_vaporisation
Key Fact: 1st law: DeltaU = Q + W; W = β«PdV (work done ON gas); Q +ve into system, W +ve on system
Key Fact: Ideal gas: pV = nRT = NkT; Boyle pβ1/V (isothermal), Charles VβT (isobaric), Pressure pβT (isochoric)
Key Fact: Kinetic theory: pV = β
Nm<c^2> -> p = β
Ο<c^2>; <c^2> = 3RT/M
Key Fact: RMS speed: c_rms = sqrt(3RT/M); M = molar mass in kg/mol
Key Fact: Degrees of freedom: monatomic 3 (translational); diatomic 5 (+2 rotational) at room temp
Key Fact: Equipartition: each quadratic term contributes Β½kT per molecule
π― Learning Objectives
Distinguish heat, internal energy, and temperature Use specific heat capacity c and specific latent heat L Apply first law: DeltaU = Q + W (sign conventions) Use ideal gas laws: Boyle, Charles, Pressure, Combined, PV = nRT Understand kinetic theory: pressure from molecular collisions Relate microscopic (molecular) to macroscopic (PV=nRT) Calculate root-mean-square speed: c_rms = sqrt(3RT/M) Understand degrees of freedom and equipartition of energy
π‘ Worked Example
Exam-Style Question
Question: 2 moles of ideal gas at 300 K compressed isothermally from 0.02 m^3 to 0.01 m^3. Find work done
Model Answer:
Isothermal: W = β«PdV = β«(nRT/V)dV = nRT ln(Vβ/Vβ) = 2x8.31x300xln(0.5) = -3457 J. Work done ON gas = +3457 J
β Practice Questions
Questions:
Heat to raise 500 g water from 20 deg C to 80 deg C (c=4180) 1 mole gas at 27 deg C, V=0.022 m^3. Find pressure Explain why C_p > C_v for ideal gas RMS speed of Nβ at 300 K (M=0.028 kg/mol) Derive pV = β
Nm<c^2> from momentum change on wall
π Past Papers & Exam Resources
π Further Reading & Resources
β Particles and Quantum Physics
β Back to Physics Overview
Gravitational, Electric and Magnetic Fields β